Zusammenfassung

A new method for the assessment of the filterability in membrane bioreactors was tested for five months in four MBR units in Berlin. The new method BFM (Berlin Filtration Method) for filterability assessment uses a small membrane filtration test cell which can be submerged directly in the biological tanks to determine the filterability of the activated sludge in-situ. The test cell contains an aerated flat-sheet membrane which operates at similar conditions as in the plant. Filterability is expressed in terms of critical flux obtained by performing flux-stepping experiments. The ultimate goal of monitoring the filterability with the device is to detect in real time fouling occurrences due to changes in sludge composition and to adapt accordingly the operating conditions. The usefulness of the device for this purpose was evaluated for five months after monitoring four MBR plants in Berlin with different activated sludge characteristics (MLSS from 5 to 21 g/L, SRT 12–35d and COD in the supernatant 30–400 mg/L). The first results show a good agreement between the filterability of the sludge with the portable filtration test cell and the filtration performance of the plant. Critical flux values varied between 3 and 30L/m2 h during the studied period. Useful information concerning the irreversibility of the fouling was provided by looking at the hysteresis curve of the flux-stepping experiments.

Zusammenfassung

Numerous papers have been published studying the causes of fouling in membrane bioreactors (MBRs) and searching for a universal fouling indicator. Unfortunately, as these studies were performed using various set-ups and operating conditions (different membranes, sludge retention time (SRT), hydraulic conditions and diverse feed wastewaters, etc.), the results in terms of fouling rates and the infl uence of individual parameters rarely match up. In order to obtain a signifi cant database of comparable results from different plants, an intensive monitoring campaign of four MBR systems started in 2007 in Berlin. In these units, 14 parameters were monitored on a weekly basis over 10 months to characterise the mixed liquor and the corresponding permeability, including the novel parameter transparent exopolymer particles (TEP), which represent a specially sticky fraction of the extracellular polymeric substances (EPS). By performing statistical analyses it was demonstrated that there is no unique fouling indicator, and origins of fouling must be searched in the combination of several parameters using multivariable analysis. Applying a multiple regression the critical fl ux values could be correlated with four parameters (temperature, nitrate, bound and soluble TEP) measured in the activated sludge for 95% of the data.

Zusammenfassung

Three different methods for fi ltration characterization in Membrane Bioreactor (MBR) systems were compared. These were the Delft Filtration Characterization Method (DFCm), the Berlin Filtration Method (BFM) and an ex situ side-stream fi ltration test cell for the determination of the critical fl ux. The ex situ fi ltration test cell and the DFCm fi lter activated sludge from a tank, while the BFM works in situ with a test cell directly submerged into the biological tank at similar operational conditions to a typical MBR plant. The mixed liquor of four different MBR units was characterised several times with the three fi ltration methods. The three tested methods seemed to agree in the classifi cation of the tested mixed liquors in terms of fi lterability except for one of the tested activated sludges. Additionally, three critical fl ux protocols were studied using the BFM fi ltration test cell. The fi rst consisted in the classical fl ux-step method, the second included relaxation between fi ltration steps and in the third protocol, 2 min fi ltration at a fi xed fl ux were performed before every fi ltration step. The last protocol was selected as the most representative of full scale MBR operation and the most interesting one for giving valuable information about the irreversibility of the fouling.

Zusammenfassung

A continuous monitoring, using UV-VIS spectrometers, was carried out in Berlin from 2010 to 2012. It combined (i) continuous measurements of the quality and flow rates of combined sewer overflows (CSO) at one main CSO outlet downstream of the overflow structure and (ii) continuous measurements of water quality parameters at five sites within the urban stretch of the receiving River Spree. Locally, the collection of data aims at (i) characterizing CSO emissions, (ii) assessing the local dynamics and intensity of CSO impacts on the river and (iii) calibrating sewer and river water quality models being part of a planning tool for future CSO management in Berlin (Riechel et al., 2011). UV-VIS spectrometers are in-situ probes, which measure absorbance spectra ranging from UV to visual wavelengths. Concentrations, such as chemical oxygen demand (COD), are calculated from these spectra. Due to the varying composition of waste and river water a local calibration is required to enhance the measurement quality. According to Gamerith et al. (2011), manufacturer global calibration can lead to systematic error up to 50% for COD measurements.

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