In the initial phase of the project "Organic Trace Substances Relevant for Drinking Water – Assessing their Elimination through Bank Filtration (TRACE)" the total herbicide glyphosate was classified as highly relevant for further investigations [Chorus & Wessel 2007]. Glyphosate is one of the most widely used and distributed herbicides in the world. Even though it has been on the market since 1974 its use increased with the expiry of the patent at the beginning of the 1990s, in the context of “soil conserving” agriculture (no ploughing) and with the introduction of glyphosate resistant, genetically manipulated cultures like corn, soy beans and cotton wool in 1997. To estimate the occurrence of glyphosate and its main metabolite AMPA in the surroundings of Berlin samples from 22 surface water sites were analysed within this study. In 5 samples the glyphosate concentration was above the European threshold for herbicides of 0.1 µg/L in drinking water. Up to 70 % of Berlin’s drinking water is produced via bank filtration and aquifer recharge characterized by comparatively low flow velocities (< 1 m/d), long contact times (3-6 months) and mainly anoxic redox conditions. To evaluate the potential of bank filtration to protect the drinking water from glyphosate contaminations an experimental study was conducted in the second phase of the TRACE project. Three enclosures at the UBA’s center for aquatic simulations were dosed with three different concentration levels (average concentration: 0.7, 3.5 and 11.6 µg/L) over a time period of 14 days. The effluent was sampled daily for 34 days. Glyphosate and AMPA were analysed applying the HPLC method according to the German Standard DIN 38407-22/2001. In parallel the applicability of the ELISA kit of the company Abraxis was tested without adequate results. The one-dimensional substance transport model VisualCXTFit was applied to obtain substance specific parameters of glyphosate and hydrodynamic parameters of the filter substrate from observed and measured breakthrough curves. The obtained results show that the breakthrough of glyphosate was retarded remarkably (retardation coefficient (R): 18.3 to 25) despite of the initially postulated low adsorption potential of the sandy filter substrate. Also a significant reduction, probably due to degradation was observed (1st order decay-rate (alpha): 0.069 to 0.092 d-1). In addition to the semi-technical scale enclosure experiments laboratory and lysemeter tests were carried out to investigate the processes responsible for glyphosate removal during subsurface passage. The laboratory experiments yielded a KF-value of 1.8998 mgLkg-1 and a Freundlich exponent of 0.4805, from which a retardation coefficient of 53.4 was calculated for a glyphosate concentration of 20 µg/L. Furthermore, delayed degradation under sub-oxic conditions could be observed. The lysemeter experiments ensured no glyphosate breakthrough in the effluent of a 2 m thick column of fine to medium sandy material within 7 months. The data obtained in this project prove that there is a potential of bank filtration to eliminate the herbicide glyphosate: Taking into account that glyphosate concentrations in surface water are highly variable a good protection of the drinking water source by bank filtration especially in respect to peak concentration is ensured. However, adsorption and degradation parameters obtained in the laboratory and semi-technical experiments vary significantly due to the difficulty to imitate natural conditions in the laboratory. Therefore the experimental study of the project TRACE emphasises the need to conduct semi-technical experiments in a near-natural environment to evaluate the risk of contamination.

The combination of advanced oxidation (e.g. ozonation) and subsurface passage could overcome known limitations of MAR techniques with respect to dissolved organic carbon (DOC) and trace organics removal. The objective of the OXIRED project is to assess possibilities and limitations as well as practicability and technical feasibility of different combinations of advanced oxidation and subsurface passage with respect to this topic. As part of the first project phase, existing data on subsurface removal of organic trace substances was evaluated in order to identify substances that should be targeted in laboratory and technical scale experiments. This report summarizes the outcomes of this evaluation.

The Aquisafe project aims at mitigation of diffuse pollution from agricultural sources to protect surface water resources. The first project phase (2007-2009) focused on the review of available information and preliminary tests regarding (i) most relevant contaminants, (ii) system-analytical tools to assess sources and pathways of diffuse agricultural pollution, (iii) the potential of mitigation zones, such as wetlands or riparian buffers, to reduce diffuse agricultural pollution of surface waters and (iv) experimental setups to simulate mitigation zones under controlled conditions. The present report deals with (iii) and has the purpose to provide a brief overview of the current state of knowledge related to the role of riparian zones as best management practices for water quality improvement at the watershed scale. Research indicates that landscape hydrogeological characteristics such as topography and surficial geology influence both riparian zone hydrology and biogeochemistry. Topography, depth to a confining layer and soil hydraulic conductivity all affect groundwater input to riparian zones and the water table fluctuation regime throughout the year. Research also indicates that although most biologically mediated reactions in soil are redox dependant, landscape hydrogeology, by affecting riparian hydrology, affects the redox conditions in the soil profile. In turn, microbial processes and changes in element concentrations are predictable as a function of the redox state of the soil.Variations in biogeochemical conditions directly affect the fate of multiple contaminants in riparian systems. In particular, variations in soil redox potential in riparian zones can affect the evolution of numerous contaminants and solutes within riparian zones like pesticides, phosphorus, NO3-, N2O, NH4+, SO42-, CH4, Fe2+/Fe3+ or Dissolved Organic Carbon (DOC). Of all the solutes/contaminants mentioned above, nitrate is one of the most important concerning water quality in many areas of the US and Western Europe. Consequently, many studies have investigated nitrate removal in riparian systems. Depending on site conditions, nitrate retention generally varies between 60 and 90 %; however, there are situations where nitrate removal is less or even where a riparian zone becomes a source of N to the stream. Although the riparian literature is clearly dominated by nitrate removal studies, many studies also focus on phosphorus, sediments, pesticides, chloride, bromide and bacteria. Although there are situations where riparian zones have been shown to be sources of P, Atrazine, bromide, E. coli or E. streptococci bacteria, riparian zones generally contribute to the reduction of most contaminants in subsurface flow and overland flow. Nevertheless, although conditions favorable to the reduction or oxidation of a given contaminant at the microbial level are often known, more research needs to be conducted to determine the variables controlling the fate of contaminants other than nitrate in soil at the riparian zone scale.Finally, although many studies have investigated the hydrological and biogeochemical functioning of riparian zones in the past few decades, much research remains to be conducted in order to quantify and predict the impact of riparian zones on water quality at the watershed scale in a variety of climatic and hydrogeological settings. In particular, better strategies and/or tools to generalize riparian function at the watershed scale need to be developed. Particular areas where research is needed to achieve this goal include: 1) the development of strategies to quantify and model the cumulative impact of individual riparian zones on water quality at the watershed scale; 2) a better quantification of the importance of spatial and temporal variability in hydrologic and biogeochemical riparian functioning relative to annual nutrient transport; 3) a better understanding of the role of vegetation in terms of its impact on riparian biogeochemical processes and the response of these processes to manipulations of vegetative cover; 4) a better understanding of the impact of human activities and infrastructure on riparian zone function in both urban and rural landscapes; 5) a better understanding of the fate of emerging contaminants in riparian systems.

In rural areas, small wastewater treatment plants (SWWTP) are a cost-efficient solution to sewage disposal issues. In Europe, small WWTPs are defined as plants for treating domes- tic wastewater up 50 PE. In Germany, about 2.2 million SWWTPs are in operation or are being installed. In France about 10 to 12 million people are served by decentralised sys- tems. There are many different technical solutions on the market, ranging from artificial wetlands, reed bed filters to activated sludge systems. All systems available on the European market have to meet the EU-Certification EN 12566-3, which regulates a minimum standard of op- eration reliability and purification limits. Furthermore, additional guidelines have to be con- sidered, depending on national and regional specifications. There is still a lack of information about performance, operation reliability and maintainability of the different types of SWWTP under real operating conditions. These parameters are however, of particular importance to both customers and service providers. To fill this gap, during a duration time of 14 month in this study 12 different treatment systems were simultaneously compared and evaluated un- der real operating conditions. The study delivers now detailed information about the perfor- mances of different plant models with regard to purification capacity, effluent values, operat- ing expenditures, sludge treatment etc. The results will be published in a user guide. The study was performed at the Training and Demonstration Centre for Decentralised Sew- age Treatment (BDZ) in Leipzig with a special range of small wastewater treatment plant, already installed at BDZ for training purposes as well as two additional plants, which has been installed there especially for the compass study.

WELLMA-1, WP 1.2 includes a statistical analysis of Berlin and French well data. The aim is to identify parameters by which the extent of iron related clogging can be assessed and which can be used for grouping the wells for further investigations. The data analysis is based on data on well construction, water chemistry and well operation for about 615 wells in Berlin and 47 in France. The approach is first to do a descriptive analysis of the datasets. It shows amongst others that the French data are not extensive enough to be included in further statistical analysis. They were therefore interpreted individually and added as annex to the report. In the second step, a reliable indicator for iron related clogging in the Berlin wells is identified. This is done by testing the significance of differences in parameters recommended by BWB (Qs, number of H2O2-treatments and results of TV-camera inspections) that indicate either intense clogging or no clogging. The analysis of the reduced dataset reveals that TV-camera inspections are the most reliable cloggingindicator for the Berlin wells for statistical analysis with the current database. Thirdly, the relation of all available constructional, hydro-chemical and operational parameters is checked for four different stages of clogging indicated by the TV-camera inspections. It can be stated that most wells reveal increasing clogging with increasing well age and decreasing depth of the first filter. Clogged wells are characterized often by lower iron and higher manganese and nitrate concentrations, a higher mean total discharge and more operating hours than wells without clogging indication. Finally, the clogging indicator is evaluated by a multiple linear regression. For this, the dependent variable clogging is linked to the ten variables, which are obviously related to clogging processes. Although all comprised parameters are partly related to the clogging intensity of the wells, only well age, depth of the first filter, iron and manganese concentrations as well as operating hours and total discharge have an explanatory value for clogging. However, their total explanatory value of 20% of the variance in clogging is low. Either the most relevant parameters to identify clogging are missing or the selected parameters reveal too much data variability. This can be due to temporal and depth oriented variations what could not be included in the recent analysis. Measurements in mixed raw water cannot characterize all processes involved in iron related clogging. Therefore, several recommendations of well operation and monitoring are given to improve the explanatory power of the data. The most important ones are the development of a more detailed matrix for the evaluation of well condition by TV-camera inspections and an improvement of measurements of specific capacity Qs by constant discharge rates and fully documented initial step pumping tests. Groups of wells that would be useful for more detailed field investigations and further data analysis are: (i) wells with different depth of the first filter, (ii) wells with significant differences in mean discharges (and similar construction and number of switchings), (iii) wells with different amounts of switchings, (iv) wells with similar number of switchings but different filter lengths or pump capacities and (v) wells of different age, but otherwise same construction and operational characteristics.