Managed aquifer recharge (MAR) provides efficient removal for many organic compounds and sum parameters. However, observed in situ removal efficiencies tend to scatter and cannot be predicted easily. In this paper, a method is introduced which allows to identify and eliminate biased samples and to quantify simultaneously the impact of (i) redox conditions (ii) kinetics (iii) residual threshold values below which no removal occurs and (iv) field site specifics. It enables to rule out spurious correlations between these factors and therefore improves the predictive power. The method is applied to an extensive database from three MAR field sites which was compiled in the NASRI project (2002e2005, Berlin, Germany). Removal characteristics for 38 organic parameters are obtained, of which 9 are analysed independently in 2 different laboratories. Out of these parameters, mainly pharmaceutically active compounds (PhAC) but also sum parameters and industrial chemicals, four compounds are shown to be readily removable whereas six are persistent. All partly removable compounds show a redox dependency and most of them reveal either kinetic dependencies or residual threshold values, which are determined. Differing removal efficiencies at different field sites can usually be explained by characteristics (i) to (iii).

Berlin’s drinking water is produced from groundwater replenished by up to 60 % of surface water from the city’s abundant rivers or lakes using bank filtration or artificial groundwater recharge. Currently 700 production wells, located along the banks produce more than 200 Mio m³/a of drinking water, which is treated only for iron and manganese removal before distribution. This is due to the fact that different natural treatment processes (e.g. straining of particles, adsorption or biodegradation) occur during subsurface passage so that post-treatment effort is reduced. Compared to other bank filtration sites world wide, the situation in Berlin is characterized by low hydraulic conductivities but nevertheless high capacities. Interdisciplinary research projects have shown that travel times and redox conditions during subsurface passage are highly transient due to seasonal effects and discontinuous pump operation. Trace organics like pharmaceuticals and x-ray contrast media that occur in Berlin’s surface waters due to relevant shares of treated waste water are attenuated during subsurface passage to varying degree. Substances that were found to be poorly attenuated under oxic conditions or even persistent include carbamazipine, primidone, sulfamethoxazole, 1,5 NDSA, MTBE and EDTA. Under anoxic to anaerobic conditions others like phenazone and diclofenac show little removal. However, none of these substances occur at relevant concentrations in the finished drinking water due to low initial concentrations or additional removal during post-treatment. Research is currently focussing on hybrid systems combining subsurface passage with advanced drinking water treatment in order to be prepared in case higher source concentrations occur.

Natürliche und künstliche Systeme zur Infiltration von Wasser (im Englischen: Managed Aquifer Recharge) werden weltweit genutzt, um Grundwasserressourcen quantitativ oder qualitativ zu verbessern. Dies erfolgt beispielsweise bei der Uferfiltration oder künstlichen Grundwasseranreicherung zur Trinkwassergewinnung, bei der Klarwasserverregnung zur weiteren Abwasserreinigung und -nutzung oder bei der Injektion von Süßwasser als hydraulische Barriere in Salzwasserintrusionsgefährdete Grundwasserleiter. Dabei nutzt man nicht nur den mengenmäßigen Ausgleich von überbeanspruchten Grundwasserressourcen, sondern auch die Reinigungsleistung des Untergrundes für eine naturnahe und meist auch kostengünstige Wasseraufbereitung. In Berlin, wo seit über 150 Jahren Trinkwasser mittels Uferfiltration gewonnen wird, wurden in Zusammenarbeit mit den Berliner Universitäten in der Vergangenheit umfangreiche Untersuchungen zur Stoffelimination bei der Untergrundpassage durchgeführt. Diese zeigten, dass auch die Konzentrationen von organischen Spurenstoffen häufig bei der Infiltration oder weiteren Grundwasserleiterpassage zurückgehen. Eine statistische Auswertung von Beobachtungen an verschiedenen Standorten ergab, dass die Mehrheit der untersuchten Substanzen wie beispielsweise Clofibrinsäure, Diclofenac und Phenazon bevorzugt unter oxischen Bedingungen abgebaut werden oder generell eine gute Entfernung erfahren. Einige wie z.B. Carbamazipin oder Sulfamethoxazol werden vor allem unter anoxisch- bis anaeroben Bedingungen entfernt. Aus diesen Beobachtungen ergab sich die Frage, ob ein optimaler Redoxzustand bzw. eine optimal Redoxabfolge für Systeme wie Infiltrationsbecken definiert werden könnte. Erste theoretische Studien erfolgten auf der Basis verfügbarer Abbaukinetiken und unter Einbeziehung weiterer Redox-sensitiver Wasserinhaltsstoffe wie Nitrat und Eisen. Diese ergaben, dass eine Aufenthaltszeit von 30 Tagen im aeroben Milieu und 100 Tagen im anoxischen Milieu während der Untergrundpassage zu einer optimalen Entfernung Redox-sensitiver Problemstoffe führt. Jedoch können bereits 15 Tage aerobe und 2 Tage anoxische / anaerobe Untergrundaufenthalt zu einem deutlichen Rückgang dieser Stoffe führen. Generell sollte jedoch berücksichtigt werden, dass unter anoxischen bis anaeroben Bedingungen mit einer Mobilisierung geogener Spurenelemente wie Eisen und Mangan zu rechnen ist. Obwohl theoretisch eine Vielzahl an Möglichkeiten existiert, den Infiltrationsbereich, die hyporheische Zone und die Untergrundpassage im Hinblick auf eine optimierte Redoxzonierung zu modifizieren oder gar zu steuern, sind nur wenige technisch tatsächlich machbar. Weitere Untersuchungen sollen nun diejenigen Möglichkeiten identifizieren, die in die Praxis übertragbar sind und zu einer Optimierung der künstlichen und natürlichen Systeme zur Infiltration beitragen könnten.

Berlin’s drinking water is produced from groundwater replenished by 60 % from surface water from the city’s abundant rivers or lakes using bank fi ltration or artifi cial groundwater recharge. Compared to other bank fi ltration sites world wide, the situation in Berlin is characterized by low hydraulic conductivities but nevertheless high capacities. Interdisciplinary research projects have shown that travel times and redox conditions during subsurface passage are highly transient due to seasonal effects and discontinuous pump operation. Trace organics like pharmaceuticals and x-ray contrast media are attenuated during subsurface passage to a varying degree. Substances that were found to be poorly removed under oxic conditions or even persistent include carbamazepine, primidone, sulfamethoxazole, 1,5 NDSA, MTBE and EDTA. Under anoxic to anaerobic conditions others like phenazone and diclofenac show little removal. However, none of these substances occur at relevant concentrations in the fi nished drinking water due to low initial concentrations in the surface water or additional removal during post-treatment (aeration and fi ltration for iron and manganese removal).

Bank filtration (BF) and aquifer recharge (AR): aquifer storage recharge (ASR), aquifer storage transport recharge (ASTR); are natural and semi-natural methods for drinking water treatment and constitute a major barrier within water supply system. Recent investigations have shown that about 60 % of Berlin’s drinking water is produced via BF or AR (Zippel & Hannappel 2008). Most drinking water therefore originates from surface waters within the cities limits and is pumped from wells adjacent to it’s many lakes and rivers. Since more than 100 years this system has been supplying safe drinking water so that post-treatment is limited to aeration and subsequent sand filtration. Disinfection is usually not applied (SenStadtUm 2008). The research project NASRI (“Natural and Artificial Systems for Recharge and Infiltration”, KWB 2002 – 2006), funded by the Berliner Wasserbetriebe (BWB) and Veolia (VE) had the aim to characterize the specific hydraulic and hydrochemical conditions at selected BF and AR sites in Berlin and to assess the behaviour of major water constituents, trace organic substances, algal toxins and pathogens during subsurface passage. For this, field investigations at three transsects (Lake Tegel BFsite, Lake Tegel AR-site and Lake Wannsee), laboratory and technical scale experiments were carried out by 7 different working groups. The results of the investigations were documented in 6 extensive research reports and were the basis for nearly 50 scientific publications. In 2007 the IC-NASRI project (Integration & Consolidation of the NASRI outcomes) was initiated by VE and BWB in order to support the practical implementation and optimization of bank filtration and aquifer recharge for drinking water production with the experience gained during the NASRI project. The aim was to derive practical guidelines for design and operation of BF & AR systems by i) further interpretation of the NASRI data and ii) integrating experience from other BF / AR sites world wide. Although subsurface passage is characteristic to many systems of managed aquifer recharge (MAR) the investigations within IC-NASRI concentrated on systems where drinking water is produced by infiltration of surface water either from the banks of a lake / river or from infiltration ponds (or similar systems like ditches or irrigation fields). A transfer of the presented results to other MAR systems, which use different recharge methods (e.g. ASR) or different sources (e.g. treated wastewater) therefore needs to be considered carefully, even though many statements may be true for them as well. This reports aims at providing engineers and scientists involved in drinking water production by BF & AR with up-to-date information on settings of similar systems world wide and on the systems’ performance with regard to drinking water treatment. The aim was to give the reader a condensed overview of the topic whereas further details can be taken from the large number of references given in the bibliography.

Managed aquifer recharge provides efficient removal for many organic water constituents but it is a difficult task to quantify removal under field conditions: Observed concentrations often scatter and may be biased by subsurface mixing of different waters. Removal efficiency is affected by different environmental parameters, such as redox potential, travel times, threshold values, and also field site specifics. In addition, it is crucial to know the corresponding surface water concentration for all samples. We developed a method, which overcomes these difficulties, quantifies the efficiency and removal kinetics and is applicable to extensive databases. It combines both, statistical and graphical evaluation which allows the determination of precise values and also interpretation based on expert knowledge. The database of this study was collected within the NASRI project between 2002 and 2005 at two bank filtration sites (Tegel BF, Wannsee BF) and one basin aquifer recharge site (Tegel AR) in Berlin. In total, 38 organic constituents were analysed (Table 1).

The combination of advanced oxidation (e.g. ozonation) and subsurface passage could overcome known limitations of MAR techniques with respect to dissolved organic carbon (DOC) and trace organics removal. The objective of the OXIRED project is to assess possibilities and limitations as well as practicability and technical feasibility of different combinations of advanced oxidation and subsurface passage with respect to this topic. As part of the first project phase, existing data on subsurface removal of organic trace substances was evaluated in order to identify substances that should be targeted in laboratory and technical scale experiments. This report summarizes the outcomes of this evaluation.

The use of bank filtration for drinking water treatment in Europe dates back to the days of beginning industrialization in the 19th century. With regard to improved source water quality in Europe, the millennium development goals and global climate change, aquifer recharge (AR) and bank filtration (BF) need to be reassessed in terms of sustainability and their role within an integrated water resource management. Based on the IC-NASRI study comprising 194 drinking water facilities worldwide integrating aquifer recharge techniques in their treatment system, an average AR/BF site would be located in Central Europe alongside a river and is characterized by: a sandy gravel aquifer with a hydraulic conductivity of 2x10-3 m/s, a maximum aquifer thickness of 30 m, 175 m travel distance from bank to well, a travel time of 70 days and by vertical well operation with a daily capacity of 55.000 m³. A literature survey conducted within the TECHNEAU project demonstrated that for substances highly relevant to newly-industrialized or developing countries (e.g. pathogens) the removal efficiency is good. Hydro-chemical analyses from three study sites in Delhi support these results. However, it was also shown that poor surface water quality, saline groundwater or subsurface conditions leading to mobilization of trace metals like iron, manganese or arsenic may limit the applicability of AR / BF without further post-treatment. Climate change might affect the performance of AR / BF worldwide, impairing source water quality and influencing removal efficiency. However, other factors like changes in demography or land-use can impact the systems by far more severely.

Riverbank filtration (RBF) denotes the process whereby river water is induced to infiltrate into a groundwater system by well operation adjacent to banks. In Central Europe, RBF has been common practice for 100 years to produce drinking water. Due to the easy implementation and little maintenance necessary, BF has been suggested to be a useful drinking water treatment for developing and newly-industrialised countries. Experience from Europe has demonstrated that RBF is suitable to remove a range of organic and inorganic contaminants while an exhaustion of cleaning capacity has not been observed. RBF systems can mitigate shock loads and are particularly known for the efficient removal of pathogens, suspended solids and algal toxins from surface water, all being water quality parameters of high relevance in developing and newly-industrialised countries. Another benefit of RBF operation is the storage capacity which may help to balance freshwater availability in areas experiencing high variations of precipitation and run-off. This report aims at evaluating the relevance and opportunities of RBF systems to provide safe water to these countries. In order to evaluate the relevance and opportunities of RBF systems to developing and newly-industrialised countries, the report is structured to address key considerations and (i) identify prerequisites for successful RBF operation based on the experience in Central Europe and the United States, (ii) assess the removal potential of RBF for various water contaminants based on available literature, the TECHNEAU investigations in India and NASRI data from Berlin and (iii) evaluate the sustainability and relevance of RBF operation with regard to the particular needs in developing and newly-industrialised countries.

Several kinds of managed aquifer recharge techniques provide very good purification of surface water since more than 100 years. In order to maintain a reliable supply of clean water, they are becoming increasingly popular all over the world. Especially bank filtration methods require low technical effort. Exemplarily, at a test site at Lake Tegel, Berlin, Germany, the hydraulic processes of infiltration are modelled. By means of 3D long term regional and transient hydraulic modelling it was detected that the existing approaches for determining the leakance induce large errors in the water balance and describe the infiltration zone insufficiently. The leakance could be identified to be triggered by the groundwater table, causing air exchange and intrusion of atmospheric oxygen, which reduces clogging by altered redox conditions by at least one order of magnitude. This causes that changes of the groundwater table are mitigated much more than previously assumed. Taking these findings into account, a transient water balance is determined and bank filtration ratios are quantified.