Within the study “IC-Pharma” a graphical benchmark of the occurrence of 30 priority pharmaceutical active compounds (PhACs) covering different therapeutic classes such as analgesics, antibiotics, lipid lowering drugs, beta blockers, tranquilizers, and cytostatics in the urban water cycle was conducted. The results are based on an extensive data set collected during several monitoring campaigns in Berlin and the Canton Zurich. This benchmark of the occurrence of priority pharmaceuticals allows water practitioners from other sites to compare detected concentrations of priority PhACs in STP effluents, surface water and groundwater.

Over the past decade, membrane bioreactors have been increasingly implemented to purify municipal wastewater. However, even with submerged modules which offer the lowest costs, the membrane bioreactor (MBR) technology remains in most cases more expensive than conventional activated sludge processes. In addition, the European municipal MBR market is to date a duopoly of two non-European producers, despite many initiatives to develop local MBR filtration systems. In 2005, the European Commission decided to finance four projects dedicated to further technological development of MBR process: the four projects AMEDEUS, EUROMBRA, MBR-TRAIN and PURATREAT were implemented from October 2005 up to December 2009 and joined their efforts within the coalition “MBR-Network” (www.mbr-network.eu). The present report synthesises the major outcomes of the project AMEDEUS, conducted from October 2005 up to May 2009. The AMEDEUS research project aimed at tackling both issues of accelerating the development of competitive European MBR filtration technologies, as well as increasing acceptance of the MBR process through decreased capital and operation costs. The project targets the two market segments for MBR technology in Europe: the construction of small plants (semi-central, 50 to 2,000 population equivalent or p.e., standardized and autonomous), and the medium-size plants (central, up to 100.000 p.e.) for plant upgrade.

Microcystins (MCYSTs) are a group of structurally similar toxic peptides produced by cyanobacteria (“blue-green algae”) which occur frequently in surface waters worldwide. Reliable elimination is necessary when using these waters as drinking watersources.Bankfiltrationandartificial groundwaterrecharge utilize adsorption and degradation processes in the subsurface, commonlythroughsandandgravel aquifers, for the elimination of a wide range of substances during drinking water (pre-) treatment. To obtain parameters for estimating whether MCYST breakthrough is likely in field settings, we tested MCYST elimination in laboratory experiments (batch experiments, column experiments) under a range of conditions. Adsorption coefficients (kd-values) obtained from batch studies ranged from 0.2 mL/g for filter sand to 11.6 mL/g for fine grained aquifer materials with 2% fine grains (<63 µm) and 0.8% organic matter. First order degradation rates in column studies reached 1.87 d-1 under aerobic conditions and showed high variations under anoxic conditions (<0.01-1.35 d-1). These results show that, next to sediment texture, redox conditions play an important role for MCYST elimination during sediment passage. Biodegradation was identified as the dominating process for MCYST elimination in sandy aquifer material.

Within the 3.5 year ENREM project (Enhanced Nutrient REmoval in Membranebioreactors) in Berlin-Margaretenhöhe a novel and patented process was investigated to demonstrate the feasibility of a semi-decentralised solution reaching high effluent requirements set by the water authority of Berlin. This novel process could be a solution for suburban areas of Berlin which are not connected to central sewer system. The biological process combines enhanced biological phosphorus removal (EBPR) with post denitrification in MBR technology without dosing of any carbon sources. The process configuration of this demonstration plant enables advanced wastewater nutrients removal (C, P and N) and could be a promising option for wastewater treatment wherever high effluent qualities are required. A second prototype MBR system was operated in parallel, applying a different biological process, e.g. without biological phosphorus removal, enabling a comparison of these different technological approaches. The demonstration plant showed high elimination rates for COD (>95%), phosphorus (>99%) and nitrogen (up to 98%) when operated within the appropriate range of design conditions. The operational experience within the first years showed that there is a possibility for process stabilisation by changing the ratio of the process steps. For this reason the volume of the anoxic zone was enlarged by reducing the aerobic volume in Feb 2008. The positive effects could be seen on the basis of the effluent concentrations after a short period of adaptation. The membrane filtration performance was very reliable with a new cleaning strategy: Two membranes were operated alternating with an operational flux of 15 – 20 L/m²/h and a maintenance cleaning with low chemical concentration. Different cleaning agents were used in order to evaluate the cleaning efficiencies. An economical evaluation of the demonstration plant was performed in comparison to the existing wastewater treatment costs of app. 7 €/m3 by trucking away and the prototype MBR plant. Operated on the same site, the two MBR systems were used to calculate the actual costs, in relation to the effluent quality, and to perform a scale-up up to 5000 pe considering four different effluent quality classes. The results showed that the ENREM process applied in the demonstration plant is economically an alternative for plant sizes of 5000 pe and larger. For plant sizes smaller than 5000 pe, the prototype MBR system equipped with precipitation and a downstream adsorption filter for enhanced phosphorus removal proofed to be the more viable solution.

The project OXIRED was initiated to assess the potential of a combination of natural systems such as bank filtration (BF) and artificial recharge (AR) and oxidation processes in order to improve the degradability of DOC and the removal of trace organics during water treatment. In this literature study, treatment schemes, which combine subsurface passage with oxidation processes, were evaluated with regard to the potential removal of DOC and trace organics, by theoretical considerations and case study analyses. The objectives were i) to estimate the degradation of bulk organic matter and trace organics in such combined systems, ii) to assess the potential for toxic by-products and iii) to describe different possible schemes combining natural systems (BF & AR) and oxidation processes. Available data generally shows good removal of the substances identified as persistent during BF & AR by oxidation processes. Carbamazepine, for example, is poorly degradable during bank filtration, but ozonation leads to a transformation of more than 97%. If ozonation alone does not suffice, advanced oxidation processes may enhance the transformation. E.g. literature gives a values of < 50% removal of Iopamidol by ozonation. However, transformation increases up to 88% using advanced oxidation processes, such as O3/H2O2 and O3/UV. Investigations on the formation of possible toxic by-products have shown the general possibilities to control the formation of bromate by decreasing the pH, avoiding free dissolved ozone in the reactor and/or by adding H2O2. Only a low risk of exposure of the potentially forming nitrosamines in drinking water after artificial recharge could be identified. Especially the cancerogenic metabolite NDMA is degraded during subsurface passage. Three reference treatment schemes were identified: (A): surface water is treated via oxidation before infiltration into artificial recharge ponds.(B): a river bank filtration with short retention times (<5 days) is used as a pretreatment step before the successive oxidation and artificial recharge (AR). (C1/C2): oxidation is applied subsequent to subsurface passage after bank filtration and artificial recharge. Due to the possible formation of toxic by-products and the increased assimilable DOC in scheme C (Examples for C1 Mülheim Styrum-East and Le Pecq Croissy & C2 Prairie Waters Project and the Bi´eau Process) a post-treatment including disinfection after oxidation is necessary. Additional post-treatment in schemes A (implemented at Mülheim Dohne) and B depends on the redox conditions and the travel times during the subsurface passage. However, although there is a lack of practical data, the enhancement of BDOC via oxidation prior to the underground passage seems theoretically more promising than the reverse configuration. It is therefore recommended that any further experimental program in OXIRED should focus on the schemes A and B and include a cost-benefit analysis of the additional first BF step.

Over the past decade, membrane bioreactors have been increasingly implemented to purify municipal wastewater. However, even with submerged modules which offer the lowest costs, the membrane bioreactor (MBR) technology remains in most cases more expensive than conventional activated sludge processes. In addition, the European municipal MBR market is to date a duopoly of two non-European producers, despite many initiatives to develop local MBR filtration systems. In 2005, the European Commission decided to finance four projects dedicated to further technological development of MBR process: the four projects AMEDEUS, EUROMBRA, MBR-TRAIN and PURATREAT were implemented from October 2005 up to December 2009 and joined their efforts within the coalition “MBR-Network” (www.mbr-network.eu). The present report synthesises the major outcomes of the project AMEDEUS, conducted from October 2005 up to May 2009. The AMEDEUS research project aimed at tackling both issues of accelerating the development of competitive European MBR filtration technologies, as well as increasing acceptance of the MBR process through decreased capital and operation costs. The project targets the two market segments for MBR technology in Europe: the construction of small plants (semi-central, 50 to 2,000 population equivalent or p.e., standardized and autonomous), and the medium-size plants (central, up to 100.000 p.e.) for plant upgrade.

The project Aquisafe assesses the potential of selected near-natural mitigation systems, such as constructed wetlands or infiltration zones, to reduce diffuse pollution from agricultural sources and consequently protect surface water resources. A particular aim is the attenuation of nutrients and pesticides. Based on the review of available information and preliminary tests within Aquisafe 1 (2007-2009), the second project phase Aquisafe 2 (2009-2012) is structured along the following main components: (i) Development and evaluation of GIS-based methods for the identification of diffuse pollution hotspots, as well as model-based tools for the simulation of nutrient reduction from mitigation zones (ii) Assessment of nutrient retention capacity of different types of mitigation zones in international case studies in the Ic watershed in France and the Upper White River watershed in the USA under natural conditions, such as variable flow. (iii) Identification of efficient mitigation zone designs for the retention of relevant pesticides in laboratory and technical scale experiments at UBA in Berlin. The present report provides a review of the properties and existing mitigation experience of the two herbicides Atrazine and Bentazone, which will be examined exemplarily in (iii). Whereas Atrazine is clearly the pesticide of greatest concern in the USA, Bentazone is mainly an issue in Europe with an increasing tendency. The sorption of Atrazine and Bentazone on soils is moderate. Moderate sorption in combination with medium to high persistency makes these compounds relatively mobile; therefore they can usually be observed in surface waters in general and in ground waters near places of their application. First experiences show that mitigation systems can be effective measures to decrease their concentrations by supporting biotic and abiotic dissipation processes, mainly at high residence times. Adding organic matter can improve adsorption of Atrazine and Bentazone, an important dissipation process in these systems. Degradation rates for Atrazine and for Bentazone can be increased by implementing highly microbiologically active conditions which can usually be accomplished in the presence of external carbon sources. While mineralization of both herbicides is favoured in aerobic -environments significant degradation of Atrazine was also observed under anaerobic conditions. A great number of open questions remain on how to design a mitigation system which is adequate to reduce herbicides in drainage water. For instance, there is no specific information on the degradation of diluted and adsorbed forms of the herbicides, very little information about necessary residence times, adsorption constants, half lives and leaching behaviour in specific substrates or comparable designs. Moreover, the influence of nitrogen, which is present in drainage water at high concentrations, on degradation of Atrazine and Bentazone remains uncertain. Finally, the behaviour of Atrazine and Bentazone (contained in agricultural drainage water) in mitigation systems in general and in bioretention swales in particular is poorly studied. Realistically, mitigation systems would only be implemented if they also allow significant reduction of nitrates. Given the existing knowledge, systems with both aerobic and anoxic zones are likely to bring most successful results regarding both herbicides and nitrates; though they may be difficult to implement. Both for nitrates and pesticides, the presence of external organic carbon sources (with a combination of fast accessible and sustainable substrate partitions) seems to be a good basis for dissipation processes and effective reduction.

Managed aquifer recharge provides efficient removal for many organic water constituents but it is a difficult task to quantify removal under field conditions: Observed concentrations often scatter and may be biased by subsurface mixing of different waters. Removal efficiency is affected by different environmental parameters, such as redox potential, travel times, threshold values, and also field site specifics. In addition, it is crucial to know the corresponding surface water concentration for all samples. We developed a method, which overcomes these difficulties, quantifies the efficiency and removal kinetics and is applicable to extensive databases. It combines both, statistical and graphical evaluation which allows the determination of precise values and also interpretation based on expert knowledge. The database of this study was collected within the NASRI project between 2002 and 2005 at two bank filtration sites (Tegel BF, Wannsee BF) and one basin aquifer recharge site (Tegel AR) in Berlin. In total, 38 organic constituents were analysed (Table 1).

The study aims at assessing in long-term trials a gravity-driven ultrafiltration pilot plant designed for a capacity of 5 m3/d. The unit was operated in South Africa with Ogunjini surface water and was run with restricted chemical intervention or maintenance (no backflush, no aeration, no crossflow and no chemical). Under South African environmental conditions and with direct filtration of the river water and only one manual drainage of the membrane reactor every weekday, the unit could fulfil the design specification in terms of water production (5 m3/d) as long as the turbidity of the raw water remained in a reasonable level (up to 160 NTU), with a filtration flux typically 4 to 6 L/h.m² (corrected at 20°C). This value was in the same range as the lab results and was consistent with the first phase results (around 5-7 L/h.m² after biosand filtration). However, the flux dropped significantly to a range of 2 to 4 L/h.m² after a rain event resulting in a turbidity peak over several days up to > 600 NTU. This demonstrated that for variable raw water types with expected turbidity peaks above 100 NTU, a pre-treatment would be required for the system (biosand filter or other). The performance of microbiological tests confirmed the integrity of the membrane and the ability of the system to achieve complete disinfection.