This bachelor thesis examines the influence of precipitation events and urban stormwater runoff on the concentrations of persistent and mobile substances (PM) in Berlin's surface waters. The analysis includes concentrations of 69 substances from four substance groups (VOCs, PAHs, PFAS, pesticides) that were recorded at 24 surface water sampling sites. Using precipitation data from 32 locations in Berlin, the concentrations were categorized according to dry weather, rain, and heavy rain influence. Statistical analyses for comparing these categories were performed using the Kruskal-Wallis and Dunn tests. Additionally, the concentrations in the surface waters were compared to those in Berlin's stormwater runoff using box-whisker plots.

13 of the investigated substances show significantly higher concentrations during rainfall or heavy rain events. This can be attributed to the input of these substances into surface waters through rainwater runoff. Particularly PAHs show notable concentration increases in Berlin's surface waters during precipitation events. PFOA and PFOS, two representatives of the PFAS group, exhibit a more complex behavior pattern depending on precipitation events. During light rainfall, their concentrations in surface waters decrease, while heavy rain events lead to increased concentrations. For pesticides and VOCs, the results are less conclusive, partly due to limited data availability.

This analysis provides valuable insights into the transport of various substance groups within the urban water cycle. The findings expand the scientific basis for developing targeted protection measures for urban waters.